catena-Poly[[dibromomercury(II)]-μ-1,5-bis(benzylsulfanyl)pentane-κ2S:S′]
✍ Scribed by Yu, Qun ;Tao, Ying ;Li, Jian-Rong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 100 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title complex, [HgBr 2 (C 19 H 24 S 2 )] n , has a single-chain structure in which adjacent HgBr 2 units are linked by bridging ligands. The Hg II centre has a distorted tetrahedral coordination environment formed by two Br À anions and two S atoms from distinct ligands.
📜 SIMILAR VOLUMES
The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br
The Ni atom in the zigzag polymeric title complex, [Ni(C~4~H~7~OS~2~)~2~(C~12~H~12~N~2~)]~__n__~, is situated on a twofold axis and the bridging ligand situated about a centre of inversion. The structure features a distorted octahedral __cis__-NiN~2~S~4~ coordination geometry defined by two chelatin