The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br
catena-Poly[[bromomercury(II)]-di-μ-bromo-κ4Br:Br-[bromomercury(II)]-μ-1,4-bis(benzylsulfanyl)butane-κ2S:S′]
✍ Scribed by Che, Guang-Bo ;Liu, Chun-Bo ;Cui, Yun-Cheng ;Li, Chuan-Bi
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 155 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title complex, [HgBr 2 (C 19 H 24 S 2 )] n , has a single-chain structure in which adjacent HgBr 2 units are linked by bridging ligands. The Hg II centre has a distorted tetrahedral coordination environment formed by two Br À anions and two S atoms from distinct ligands.
(2-pyridylmethyl)amine-j 3 N,N 0 0 0 ,N 0 0 00 0 0 ]nickel(II)} dibromide
Powder X-ray study T = 293 K Mean '(N±C) = 0.016 A Ê R factor = 0.054 wR factor = 0.090 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.