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Poly[[μ-1,4-bis(ethyl­sulfanyl)butane-κ2S,S′]di-μ-bromo-mercury(II)]

✍ Scribed by Liu, Chun-Bo ;Che, Guang-Bo ;Cui, Yun-Cheng ;Li, Chuan-Bi

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
127 KB
Volume
61
Category
Article
ISSN
1600-5368

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The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br

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The crystal structure of [HgBr 2 (Pyo)] n (Pyo = pyridazine, C 4 H 4 N 2 ) consists of strands of octahedrally coordinated mercuric centers asymmetrically bridged by bromide and connected by the two neighboring N atoms of pyridazine molecules to complete the octahedral coordination of mercury. The H