𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly­[mercury(II)-di-μ-bromo-μ-pyridazine-κ2N:N′]

✍ Scribed by Nockemann, Peter ;Meyer, Gerd

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
310 KB
Volume
60
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The crystal structure of [HgBr 2 (Pyo)] n (Pyo = pyridazine, C 4 H 4 N 2 ) consists of strands of octahedrally coordinated mercuric centers asymmetrically bridged by bromide and connected by the two neighboring N atoms of pyridazine molecules to complete the octahedral coordination of mercury. The Hg atoms lie on inversion centers.

📜 SIMILAR VOLUMES

Poly­[[di­bromo­mercury(II)]-di-μ-pyrazi
Poly­[[di­bromo­mercury(II)]-di-μ-pyrazine-κ4N:N′]
✍ Nockemann, Peter ;Meyer, Gerd 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 409 KB

The crystal structure of [HgBr 2 (Pyp) 2 ] n (Pyp = pyrazine, C 4 H 4 N 2 ) consists of almost linear HgBr 2 molecules which are linked by pyrazine molecules to form double strands of a coordination polymer in the [010] direction. The Hg and Br atoms lie on mirror planes.

catena-Poly[[dichloro­zinc(II)]-μ-1,2-di
catena-Poly[[dichloro­zinc(II)]-μ-1,2-di-4-pyridylethyl­ene-κ2N:N′]
✍ Qin, Chuang-Ye ;Xu, Jing-Wei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 129 KB

In the title compound, [ZnCl~2~(C~12~H~10~N~2~)]~__n__~, the Zn^II^ ion displays a tetrahedral coordination geometry. Each 1,2-di-4-pyridylethylene ligand is located on an inversion center and bridges Zn^II^ ions, forming a zigzag polymeric chain. Weak C—H...Cl hydrogen bonding is observed in the cr

catena-Poly[[dichloridonickel(II)]-μ-1,2
catena-Poly[[dichloridonickel(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]
✍ Zhang, Ling ;Yu, Jian 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 899 KB

The title compound, [NiCl 2 (C 12 H 12 N 2 )] n , is a nickel complex polymer bridged by 1,2-bis(4-pyridyl)ethane ligands. The Ni II center is coordinated in a distorted tetrahedral geometry by two Cl ligands and two N atoms from two 1,2-bis(4-pyridyl)ethane ligands, forming a one-dimensional zigzag

catena-Poly[[bromo­mercury(II)]-di-μ-bro
catena-Poly[[bromo­mercury(II)]-di-μ-bromo-κ4Br:Br-[bromo­mercury(II)]-μ-1,3-bis­(ethyl­sulfan­yl)propane-κ2S:S′]
✍ Cui, Yun-Cheng ;Che, Guang-Bo ;Lin, Xian-Feng ;Liu, Chun-Bo 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br