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1,6-Bis(phenyl­sulfan­yl)hexa­ne

✍ Scribed by Awaleh, Mohamed Osman ;Badia, Antonella ;Brisse, François

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
168 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 16 H 18 S 2 (or L 6 ), crystallizes with two half-molecules in the asymmetric unit and each independent molecule lies about a crystallographic center of symmetry. The aliphatic segment of this ligand is in an all-trans conformation.

📜 SIMILAR VOLUMES

1,2-Bis(phenyl­sulfan­yl)ethane
1,2-Bis(phenyl­sulfan­yl)ethane
✍ Hou, Bao-Hong ;Zhou, Li-Na ;Yin, Qiu-Xiang ;Wang, Jing-Kang ;Chen, Wei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 109 KB

In the title compound, C 14 H 14 S 2 , there is a centre of inversion at the mid-point of the central C-C bond. Excluding H atoms, the molecule adopts an anti conformation, with a planar -S-CH 2 -CH 2 -S-spacer unit. The dihedral angle between the phenyl ring and the S-C-C-S chain is 84.52 (18) .

1,6-Bis(1-methyl-1H-tetra­zol-5-ylsulfan
1,6-Bis(1-methyl-1H-tetra­zol-5-ylsulfan­yl)hexa­ne
✍ She, Jiang-Bo ;Zhang, Guo-Fang ;Dou, Yin-Li ;Fan, Xue-Zhong ;Li, Ji-Zhen 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 165 KB

The molecule of the title compound, C 10 H 18 N 8 S 2 , lies on a twofold rotation axis. Methyl C atoms contact N atoms of adjacent molecules through C-HÁ Á ÁN hydrogen bonds [3.445 (3) A ˚] in a molecular layer. In addition, the layers are linked by weak SÁ Á ÁS interactions [3.636 (3) A ˚].