The title compound, [RhCl(C~19~H~17~P)~2~(CO)], can be characterized as a Vaska-type complex containing a diphenyl(4-tolyl)phosphine ligand. The rhodium(I) metal centre has a square-planar coordination. The molecule is disordered, with the Rh atom lying on an inversion centre. The most important bon
Chlorobis[diphenyl(p-tolyl)phosphine]copper(I)
✍ Scribed by Steyl, Gideon
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 117 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The centrosymmetric title compound, [PdCl~2~(C~19~H~17~P)~2~], crystallizes with a square-planar geometry about the Pd^II^ metal centre. The most important bond distances include Pd—P (__trans__ P) of 2.3404 (9) Å and Pd—Cl (__trans__ Cl) of 2.2977 (12) Å. Weak intra- and intermolecular hydrogen bon
H atoms were included using a riding model with fixed C-H bond lengths of 0.95 (phenyl), 0.99 (methylene), 1.00 A ˚(CHCl 3 ); U iso (H) values were fixed at 1.2 times U eq of the parent atom. To improve refinement stability, a total of 562 restraints were applied to C atom displacement parameters (s
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.