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Chloro­bis[diphen­yl(p-tol­yl)phosphine]copper(I)

✍ Scribed by Steyl, Gideon


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
117 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


trans-Carbonyl­chloro­bis[diphen­yl(4-to
✍ Kirsten, Leo ;Steyl, Gideon ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 137 KB

The title compound, [RhCl(C~19~H~17~P)~2~(CO)], can be characterized as a Vaska-type complex containing a diphenyl(4-tolyl)phosphine ligand. The rhodium(I) metal centre has a square-planar coordination. The molecule is disordered, with the Rh atom lying on an inversion centre. The most important bon

trans-Dichloro­bis[diphen­yl(p-tol­yl)­p
✍ Steyl, Gideon ;Kirsten, Leo ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 167 KB

The centrosymmetric title compound, [PdCl~2~(C~19~H~17~P)~2~], crystallizes with a square-planar geometry about the Pd^II^ metal centre. The most important bond distances include Pd—P (__trans__ P) of 2.3404 (9) Å and Pd—Cl (__trans__ Cl) of 2.2977 (12) Å. Weak intra- and intermolecular hydrogen bon

cis-Bis[diphen­yl(phenyl­sulfanylmeth­yl
✍ Jones, Peter G. ;Fernández, Eduardo J. ;López-de-Luzuriaga, José M. ;Laguna, Ant 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 138 KB

H atoms were included using a riding model with fixed C-H bond lengths of 0.95 (phenyl), 0.99 (methylene), 1.00 A ˚(CHCl 3 ); U iso (H) values were fixed at 1.2 times U eq of the parent atom. To improve refinement stability, a total of 562 restraints were applied to C atom displacement parameters (s