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cis-Bis[diphen­yl(phenyl­sulfanylmeth­yl)diphenyl­phosphine-κP]bis­(penta­fluoro­phen­yl)gold(III) perchlorate chloro­form solvate

✍ Scribed by Jones, Peter G. ;Fernández, Eduardo J. ;López-de-Luzuriaga, José M. ;Laguna, Antonio


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
138 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


H atoms were included using a riding model with fixed C-H bond lengths of 0.95 (phenyl), 0.99 (methylene), 1.00 A ˚(CHCl 3 ); U iso (H) values were fixed at 1.2 times U eq of the parent atom. To improve refinement stability, a total of 562 restraints were applied to C atom displacement parameters (similarity and rigid-bond restraints) and local ring symmetry (planarity and similarity of distances). The Flack metal-organic papers m1998 Jones et al. [Au(C 6 F 5 ) 2 (C 19 H 17 PS) 2 ]ClO 4 ÁCHCl 3