Trichloro(perdeuteroacetonitrile)bis(triphenylphosphine)rhodium(III)
✍ Scribed by Clegg, William ;Scott, Andrew J. ;Norman, Nicholas C. ;Robins, Edward G. ;Whittell, George R.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 258 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1
Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [RhCl(PBz 3 ) 2 (CO)] [PBz 3 = tribenzylphosphine, P(C 7 H 7 ) 3 ], which is the ®rst reported tribenzyl-phosphine±rhodium(I) structure, has pseudo-square-planar coordination geometry, with RhÐP bond distances of 2.3164 (15) and 2.3156 (16) A Ê . The RhÐCl, RhÐC and CÐ O bond dis
The crystal structure of the title compound, [IrCl 2 H-(C 18 H 15 P) 2 (CO)] or [IrCl 2 (H)(CO)(PPh 3 ) 2 ], has been determined. The compound is an octahedral iridium(III) complex with trans phosphine and cis chloride ligands. The molecule sits on a crystallographic twofold axis.