Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Chloro-cis-dihydro-mer-tris(triphenylphosphine)rhodium(III) dichloromethane hemisolvate
✍ Scribed by Clegg, William ;Elsegood, Mark R. J. ;Norman, Nicholas C. ;Pickett, Nigel L.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 214 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, [IrCl 2 H-(C 18 H 15 P) 2 (CO)] or [IrCl 2 (H)(CO)(PPh 3 ) 2 ], has been determined. The compound is an octahedral iridium(III) complex with trans phosphine and cis chloride ligands. The molecule sits on a crystallographic twofold axis.
In the title compound, [Fe(C 5 H 5 )(C 4 H 9 NSi)(C 18 H 15 P)(CO)]-(CF 3 SO 3 )Á0.5CH 2 Cl 2 , the Fe II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.015 A Ê Disorder in solvent or counterion R factor = 0.038 wR factor = 0.109 Data-to-parameter ratio = 13.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.