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Carbonyl(η5-cyclo­penta­dienyl)(tri­methyl­silyl isocyanide)(tri­phenyl­phosphine)­iron(II) tri­fluoro­methane­sulfonate di­chloro­methane hemisolvate

✍ Scribed by Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
119 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Fe(C 5 H 5 )(C 4 H 9 NSi)(C 18 H 15 P)(CO)]-(CF 3 SO 3 )Á0.5CH 2 Cl 2 , the Fe II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the Fe-C, C-N and N-Si bond distances are 1.836 (3), 1.162 (4) and 1.792 (3) A ˚, respectively.

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