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Di­carbonyl(η5-cyclo­penta­dienyl)(tri­methyl­silyl isocyanide)­iron(II) tri­fluoro­methane­sulfonate

✍ Scribed by Nakazawa, Hiroshi ;Itazaki, Masumi ;Owaribe, Mari


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
123 KB
Volume
61
Category
Article
ISSN
1600-5368

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In the title compound, [Fe(C 5 H 5 )(C 4 H 9 NSi)(C 18 H 15 P)(CO)]-(CF 3 SO 3 )Á0.5CH 2 Cl 2 , the Fe II atom is coordinated by carbonyl, triphenylphosphine, trimethylsilyl isocyanide and cyclopentadienyl ligands in a typical piano-stool structure. The Fe-C-N-Si arrangement is almost linear and the

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In Cp\*Fe(CO) 2 (n-C 3 H 6 Br), where Cp\* = 5 -C 5 (CH 3 ) 5 , the Fe atom is coordinated by a pentamethylcyclopentadienyl ligand, two carbonyl ligands and a bromoalkyl chain in a pseudooctahedral arrangement. The molecular geometry is similar to that reported for a related structure, with the alky

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Single-crystal X-ray study T = 137 K Mean '(C±C) = 0.005 A Ê R factor = 0.048 wR factor = 0.134 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.