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Bromo­propyl­di­carbonyl­(η5-penta­methyl­cyclo­penta­dienyl)­iron(II)

✍ Scribed by Friedrich, Holger B. ;Onani, Martin O. ;Rademeyer, Melanie

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
156 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In Cp*Fe(CO) 2 (n-C 3 H 6 Br), where Cp* = 5 -C 5 (CH 3 ) 5 , the Fe atom is coordinated by a pentamethylcyclopentadienyl ligand, two carbonyl ligands and a bromoalkyl chain in a pseudooctahedral arrangement. The molecular geometry is similar to that reported for a related structure, with the alkyl chain in an all-trans conformation and a FeÐC(alkyl) bond length of 2.057 (3) A Ê . In the crystal structure, the molecules pack in layers.

📜 SIMILAR VOLUMES

Di­carbonyl­(η5-cyclo­penta­dienyl)­iodo
Di­carbonyl­(η5-cyclo­penta­dienyl)­iodo­iron(II)
✍ Zeller, Matthias ;Lazich, Evelyn ;Hunter, Allen D. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 584 KB

Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.005 A Ê R factor = 0.026 wR factor = 0.059 Data-to-parameter ratio = 18.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e. In the title compound, [Fe(C 5 H 5 )I(CO) 2 ], there a