Dicarbonyl(η5-cyclopentadienyl)iodoiron(II)
✍ Scribed by Zeller, Matthias ;Lazich, Evelyn ;Hunter, Allen D.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 584 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.005 A Ê R factor = 0.026 wR factor = 0.059 Data-to-parameter ratio = 18.4
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In the title compound, [Fe(C 5 H 5 )I(CO) 2 ], there are two independent molecules in the asymmetric unit. They exhibit a three-legged-piano-stool geometry.
📜 SIMILAR VOLUMES
In Cp\*Fe(CO) 2 (n-C 3 H 6 Br), where Cp\* = 5 -C 5 (CH 3 ) 5 , the Fe atom is coordinated by a pentamethylcyclopentadienyl ligand, two carbonyl ligands and a bromoalkyl chain in a pseudooctahedral arrangement. The molecular geometry is similar to that reported for a related structure, with the alky
The title compound, 1,2-bis(4-nitrophenyl)ferrocene, [Fe(C 5 H 5 )(C 17 H 11 N 2 O 4 )], crystallizes with the planes of the two vicinal 4-nitrophenyl rings subtending angles of 46.04 (6) and 36.30 (7) at the plane of the substituted cyclopentadiene ring of the ferrocene moiety.