𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hydridodi­chloro­tris­(methyl­di­phenyl­phosphine)­rhodium(III) di­chloro­methane trisolvate

✍ Scribed by Clegg, William ;Scott, Andrew J. ;Norman, Nicholas C. ;Robins, Edward G. ;Whittell, George R.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
199 KB
Volume
58
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


📜 SIMILAR VOLUMES


Carbonyl­di­chloro­hydridobis­(tri­pheny
✍ Charmant, Jonathan P. H. ;Norman, Nicholas C. ;Orpen, A. Guy ;Whittell, George R 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 162 KB

The crystal structure of the title compound, [IrCl 2 H-(C 18 H 15 P) 2 (CO)] or [IrCl 2 (H)(CO)(PPh 3 ) 2 ], has been determined. The compound is an octahedral iridium(III) complex with trans phosphine and cis chloride ligands. The molecule sits on a crystallographic twofold axis.

Di­bromo­di­carbonyl­bis­(tri­phenyl­pho
✍ Lozano Diz, Enrique ;Therrien, Bruno ;Neels, Antonia ;Süss-Fink, Georg 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 193 KB

Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Tris­(tri­phenyl­silyl)­phosphate di­chl
✍ Ferguson, George ;O'Leary, Brian J. ;Spalding, Trevor R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 236 KB

The structure of the title monomeric phosphosilicate, C 54 H 45 O 4 PSi 3 Á0.263CH 2 Cl 2 or (Ph 3 SiO) 3 POÁ0.263CH 2 Cl 2 , is reported and is the first of a phosphosiloxane molecule with the general formula (R 3 SiO) 3 PO. Although the three P V -O-Si angles are remarkably similar [143.57 (16), 1