Hydridodichlorotris(methyldiphenylphosphine)rhodium(III) dichloromethane trisolvate
✍ Scribed by Clegg, William ;Scott, Andrew J. ;Norman, Nicholas C. ;Robins, Edward G. ;Whittell, George R.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 199 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, [IrCl 2 H-(C 18 H 15 P) 2 (CO)] or [IrCl 2 (H)(CO)(PPh 3 ) 2 ], has been determined. The compound is an octahedral iridium(III) complex with trans phosphine and cis chloride ligands. The molecule sits on a crystallographic twofold axis.
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The structure of the title monomeric phosphosilicate, C 54 H 45 O 4 PSi 3 Á0.263CH 2 Cl 2 or (Ph 3 SiO) 3 POÁ0.263CH 2 Cl 2 , is reported and is the first of a phosphosiloxane molecule with the general formula (R 3 SiO) 3 PO. Although the three P V -O-Si angles are remarkably similar [143.57 (16), 1