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Carbonyl­di­chloro­hydridobis­(tri­methyl­phosphine)­iridium(III)

✍ Scribed by Charmant, Jonathan P. H. ;Norman, Nicholas C. ;Orpen, A. Guy ;Whittell, George R.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
143 KB
Volume
60
Category
Article
ISSN
1600-5368

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The crystal structure of the title compound, [IrCl 2 H-(C 18 H 15 P) 2 (CO)] or [IrCl 2 (H)(CO)(PPh 3 ) 2 ], has been determined. The compound is an octahedral iridium(III) complex with trans phosphine and cis chloride ligands. The molecule sits on a crystallographic twofold axis.

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Single-crystal X-ray study T = 160 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.118 Data-to-parameter ratio = 21.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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