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Chloro­[tris­(per­fluoro­phenyl)­phosphine]­gold(I)

✍ Scribed by Chen, Hsiao Wei ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
242 KB
Volume
59
Category
Article
ISSN
1600-5368

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trans-Carbonyl­chloro­bis[tris­(penta­fl
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The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1

Tris­(penta­fluoro­phenyl)­phosphine oxi
Tris­(penta­fluoro­phenyl)­phosphine oxide
✍ Nicholson, Brian K. ;Thwaite, Susanna E. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

Crystals of the title compound, (C 6 F 5 ) 3 P O or C 18 H 15 OP, have two independent molecules in the asymmetric unit, with average P O and PÐC bond lengths of 1.467 (2) and 1.817 (2) A Ê , respectively, and an average O PÐC angle of 112.9 (1) .