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Bis­(tri­phenyl­phosphine)­iminium tri­carbonyl­cyclo­penta­dienyl­molybdate

✍ Scribed by Evans, Cameron ;Nicholson, Brian K. ;Oliver, Allen G.

Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
174 KB
Volume
57
Category
Article
ISSN
1600-5368

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✦ Synopsis

The crystal structure of bis(triphenylphosphine)iminium cyclopentadienyltricarbonylmolybdate, [PPN][Mo(CO) 3 ( 5 -C 5 H 5 )] (PPN + = [(PPh 3 ) 2 N] + , C 36 H 30 NP 2 ), is reported. The anion is con®gured in the piano-stool' arrangement while the cation adopts a bent con®guration about the PÐNÐP bond. An expanded-phenyl-embrace' supramolecular motif is noted in the packing of the PPN + cation.

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