In the title compound, [Cu(C~14~H~12~N~2~)~2~]C~24~H~20~B·CH~2~Cl~2~, Cu^I^ is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me~2~phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The co
(4,7-Diphenyl-1,10-phenanthroline)bis(triphenylphosphine)copper(I) tetrafluoroborate
✍ Scribed by Che, Guang-Bo ;Li, Wen-Lian ;Li, Tian-Le ;Su, Zi-Sheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 159 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Cu(C 24 H 16 N 2 )(C 18 H 15 P) 2 ]BF 4 , consists of mononuclear Cu(PPh 3 ) 2 (NN) + and BF 4 À ions (NN is 4,7diphenyl-1,10-phenanthroline). The Cu I atom is four-coordinated by two P atoms of PPh 3 groups and two N donors of two NN ligands to form a tetrahedral coordination geometry.
📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate
Ttle 1uaGncsccnce of t11c tittc c~rnplcs ICu(dppf2 ] + in rhc solid state is reported. The results are compared with tflose crf r&rcd Cut con~plcscs ami with those for /Cu(dpp)2 1' in solution.