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Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) tetra­phenyl­borate dichloro­methane solvate

✍ Scribed by Eckenhoff, William T. ;Pintauer, Tomislav

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
195 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C~14~H~12~N~2~)~2~]C~24~H~20~B·CH~2~Cl~2~, Cu^I^ is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me~2~phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The complexes form π–π stacking interactions between 2,9-Me~2~phen ligands, with a perpendicular interplanar separation of 3.652 (5) Å.

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