Tetrakis(trimethylammonioacetato-O)copper(II) bis(hexafluorophosphate)
✍ Scribed by Yang, Yang-Yi ;Chen, Xiao-Ming ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 210 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Cu atom in the title compound, [Cu(C 5 H 11 NO 2 ) 4 ](PF 6 ) 2 , shows square-planar coordination. The asymmetric unit comprises one eighth of the molecular formula.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.012 A Ê Disorder in solvent or counterion R factor = 0.043 wR factor = 0.131 Data-to-parameter ratio = 11.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Di-l-fluoro-bis[(acetonitrile){N,N 0 0 0 -bis[(dimethylamino)(morpholino)methylene]propane-1,3-diamine}copper(II)] bis(hexafluorophosphate): the first di-l-fluoro-bridged dicopper bisguanidine compound
Single-crystal X-ray study T = 130 K Mean '(C±C) = 0.005 A Ê R factor = 0.070 wR factor = 0.136 Data-to-parameter ratio = 19.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title mononuclear complex, [Cu(ClO 4 ) 2 (C 5 H 4 N 2 O 3 ) 4 ], the six-coordinated Cu II ion lies on an inversion centre and presents a slightly distorted octahedral geometry. Astacking interaction is observed between symmetry-related pyridine rings.