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Tris(1,10-phenanthroline)cobalt(II) triiodide

✍ Scribed by Tershansy, Meredith A. ;Goforth, Andrea M. ;Smith, Mark D. ;Peterson Jr, LeRoy ;zur Loye, Hans-Conrad

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
220 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthroline, and SnI 2 , where the SnI 2 reagent serves only as a source of I atoms.

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