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Tris(1,10-phenanthroline)­nickel(II) hexamolybdate

✍ Scribed by Wang, Wenju ;Xu, Lin ;Gao, Guanggang ;Wei, Yongge

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
443 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,10-phenanthroline (phen) ligands. The crystal packing is stabilized by some weak stacking interactions between neighboring phen ligands, and some C-HÁ Á ÁO interactions. The Ni atom occupies a special position with twofold symmetry.

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