Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.015 A Ê R factor = 0.043 wR factor = 0.109 Data-to-parameter ratio = 11.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tris(1,10-phenanthroline)copper(II) tricyanomethanide
✍ Scribed by Potočňák, Ivan ;Pohlová, Martina ;Wagner, Christoph ;Jäger, Lothar
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 220 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol
The title complex, {[Cd 3 (C 4 H 4 O 4 ) 3 (C 12 H 8 N 2 ) 3 ]Á4H 2 O} n , has been isolated from the hydrothermal reaction of cadmium acetate with 1,10-phenanthroline (phen) and succinic acid. The structure features two-dimensional networks formed by succinate ligands bridging Cd atoms in two diffe