The title complex, {[Cd 3 (C 4 H 4 O 4 ) 3 (C 12 H 8 N 2 ) 3 ]Á4H 2 O} n , has been isolated from the hydrothermal reaction of cadmium acetate with 1,10-phenanthroline (phen) and succinic acid. The structure features two-dimensional networks formed by succinate ligands bridging Cd atoms in two diffe
Tris(1,10-phenanthroline)zinc(II) dichromate tetrahydrate
✍ Scribed by Ejsmont, Krzysztof ;Wasielewski, Marek ;Zaleski, Jacek
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 323 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,1
The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol
The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighborin