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Aqua­bis(1,10-phenanthroline)(3-sulfonatobenzoato)manganese(II) tetra­hydrate

✍ Scribed by Yang, Teng-Jiao ;Xiao, Hong-Ping ;Zhu, Long-Guan

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
196 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighboring monomers and extensive hydrogen bonding consolidate the stability of the crystal structure.

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