𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Poly[[aqua­(1,10-phenanthroline)lead(II)]-μ3-3-sulfonatobenzoato]

✍ Scribed by Ma, Ai-Qing ;Zhu, Long-Guan ;Cai, Guo-Qiang

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
177 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, [Pb(C 7 H 4 O 5 S)(C 12 H 8 N 2 )(H 2 O)] n , each Pb II atom is coordinated by five O atoms from one water molecule and three 3-sulfonatobenzoate ligands and two N atoms from one 1,10-phenanthroline. The 3-sulfonatobenzoate ligand serves as a 3 -bridge, linking three Pb II atoms, and extends the structure into a one-dimensional ladder. The O-HÁ Á ÁO hydrogen bonds generate a twodimensional layer and enhance the stability of the structure.

📜 SIMILAR VOLUMES

Poly[aqua­(2,2′-bipyridine)(μ3-3-sulfona
Poly[aqua­(2,2′-bipyridine)(μ3-3-sulfonatobenzoato)lead(II)]
✍ Zhu, Long-Guan ;Xiao, Hong-Ping 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

In the title polymeric complex, [Pb(C 7 H 4 O 5 S)(C 10 H 8 N 2 )-(H 2 O)] n , each Pb II atom has a seven-coordinate geometry. The 3-sulfonatobenzoate ligand acts as a 3 -bridging linker, generating a one-dimensional ladder. The packing is further stabilized by an O-HÁ Á ÁO hydrogen-bonding network

Aqua­bis(1,10-phenanthroline)(3-sulfonat
Aqua­bis(1,10-phenanthroline)(3-sulfonatobenzoato)manganese(II) tetra­hydrate
✍ Yang, Teng-Jiao ;Xiao, Hong-Ping ;Zhu, Long-Guan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighborin

Poly[[[aqua­(1,10-phenanthroline)cobalt(
Poly[[[aqua­(1,10-phenanthroline)cobalt(II)]-μ3-4-bromo­isophthalato] monohydrate]
✍ Hu, Xin-Gen ;Xiao, Hong-Ping 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 291 KB

In the title compound, {[Co(C~8~H~3~BrO~4~)(C~12~H~8~N~2~)(H~2~O)]·H~2~O}~__n__~, each Co^II^ ion is six-coordinated by three O atoms from three carboxylate groups of three 4-bromoisophthalate dianions, one water molecule, and two N atoms from a 1,10-phenanthroline ligand. The coordination geometry

Bis(1,10-phenanthroline)(3-sulfonatobenz
Bis(1,10-phenanthroline)(3-sulfonatobenzoato)zinc(II) trihydrate
✍ Zhang, Li-Ping ;Zhu, Long-Guan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 202 KB

In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o