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Bis(1,10-phenanthroline)(3-sulfonatobenzoato)zinc(II) trihydrate

✍ Scribed by Zhang, Li-Ping ;Zhu, Long-Guan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
202 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand only chelates to the Zn atom using its carboxylate group. Several O-HÁ Á ÁO hydrogen bonds stabilize the crystal packing.

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Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.