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Diaqua­(1,10-phenanthroline)(3-sulfonatobenzoato)copper(II) monohydrate

✍ Scribed by Cai, Lei ;Zhu, Long-Guan


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
222 KB
Volume
61
Category
Article
ISSN
1600-5368

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(Acetyl­enedicarboxyl­ato)diaqua­(1,10-p
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In the title complex, [Cu(C 4 O 4 )(C 12 H 8 N 2 )(H 2 O) 2 ]Á2H 2 O, the Cu II centre exhibits a slightly distorted square-pyramidal coordination geometry, defined by two N atoms from a 1,10phenanthroline (phen) molecule, one O atom from an acetylenedicarboxylate dianion (ace 2À ), and two O atoms

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In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o

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The title compound, [Mn(C~7~H~4~O~5~S)(C~12~H~8~N~2~)~2~(H~2~O)]·4H~2~O, which was obtained by the reaction of MnCl~2~ with sodium hydrogen 3-sulfobenzoate and 1,10-phenanthroline, is a monomer. The coordination polyhedron of the Mn atom is a distorted octahedron. π–π Interactions between neighborin

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In the title compound, [Pb(C 7 H 4 O 5 S)(C 12 H 8 N 2 )(H 2 O)] n , each Pb II atom is coordinated by five O atoms from one water molecule and three 3-sulfonatobenzoate ligands and two N atoms from one 1,10-phenanthroline. The 3-sulfonatobenzoate ligand serves as a 3 -bridge, linking three Pb II at