Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.105 Data-to-parameter ratio = 27.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
(4,7-Dimethyl-1,10-phenanthroline)bis(pyrrolinedithiocarbamato)zinc(II)
✍ Scribed by Guo, Tengwen ;Lai, Chian Sing ;Tan, Xi Jie ;Teo, Chin Seng ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 205 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
An N 2 S 2 -donor set de®nes the approximately tetrahedral coordination environment about the zinc centre in the monomeric title compound, [Zn(S 2 CO i Pr) 2 (4,7-Me 2 phen)] or [Zn(C 4 H 7 OS 2 ) 2 (C 14 H 12 N 2 )], which has crystallographically imposed twofold rotation symmetry.
The mononuclear structure of Zn(S 2 CN(CH 2 ) 4 ) 2 (4,7-Ph 2 -1,10-phenanthroline) shows the zinc atom in each of the two independent molecules comprising the asymmetric unit to exist in a distorted octahedral geometry defined by an N 2 S 4 donor set.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [ZnCl~2~(C~26~H~20~N~2~)]·0.35H~2~O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The Zn^II^ atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions i