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(4,7-Di­methyl-1,10-phenanthroline)­bis(O-isopro­propyl­di­thio­carbonato)­zinc(II)

✍ Scribed by Soh, Shu Fang ;Lai, Chian Sing ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
197 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

An N 2 S 2 -donor set de®nes the approximately tetrahedral coordination environment about the zinc centre in the monomeric title compound, [Zn(S 2 CO i Pr) 2 (4,7-Me 2 phen)] or [Zn(C 4 H 7 OS 2 ) 2 (C 14 H 12 N 2 )], which has crystallographically imposed twofold rotation symmetry.

📜 SIMILAR VOLUMES

(4,7-Di­methyl-1,10-phenanthroline)­bis­
(4,7-Di­methyl-1,10-phenanthroline)­bis­(pyrroline­di­thio­carbamato)­zinc(II)
✍ Guo, Tengwen ;Lai, Chian Sing ;Tan, Xi Jie ;Teo, Chin Seng ;Tiekink, Edward R. T 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

μ-Bis­(di­phenyl­phosphino)­ethane-P,P′-
μ-Bis­(di­phenyl­phosphino)­ethane-P,P′-bis­[bis(O-iso­propyl­di­thio­carbonato-S,S′)­zinc(II)]
✍ Beer, Stephan ;Lai, Chian Sing ;Halbach, Tobias S. ;Tiekink, Edward R. T. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

The molecular structure of the title compound, [Zn 2 (C 4 H 7 OS 2 ) 4 (C 26 H 24 P 2 )], features two Zn(S 2 COiPr) 2 units bridged by a diphosphine ligand. The thiolate ligands are chelating but form asymmetric ZnÐS bonds, introducing considerable distortion in the coordination geometry about Zn t

Bis­(diethyl­di­thio­carbamato)(4,7-di­m
Bis­(diethyl­di­thio­carbamato)(4,7-di­methyl-1,10-phenanthroline)­cadmium(II) aceto­nitrile solvate
✍ Guo, Tengwen ;Lai, Chian Sing ;Tan, Xi Jie ;Teo, Chin Seng ;Tiekink, Edward R. T 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 201 KB

Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.105 Data-to-parameter ratio = 27.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Dichlorido(2,9-dimethyl-4,7-diphenyl-1,1
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate
✍ Qiu, Yu-E 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 725 KB

The title compound, [ZnCl~2~(C~26~H~20~N~2~)]·0.35H~2~O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The Zn^II^ atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions i