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Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate

✍ Scribed by Qiu, Yu-E

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 725 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807052580

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✦ Synopsis

The title compound, [ZnCl~2~(C~26~H~20~N~2~)]·0.35H~2~O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The Zn^II^ atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions in a tetrahedral geometry. In the structure there exist O—H...Cl hydrogen bonds and π–π interactions [centroid–centroid = 4.035 (4) Å and vertical distance = 3.883 (4) Å], which lead to the formation of one-dimensional supramolecular chains. This compound is isostructural with the CuCl~2~, NiI~2~, NiBr~2~ and PtI~2~ adducts of the ligand 9-dimethyl-4,7-diphenyl-1,10-phenanthroline.

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