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Di-μ-azido-bis­[azido(4,7-di­methyl-1,10-phenanthroline)copper(II)]

✍ Scribed by Zhao, Qihua ;Wang, Xiaofeng ;Fang, Ruibin ;Tiekink, Edward R. T.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
231 KB
Volume
59
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.003 A Ê R factor = 0.027 wR factor = 0.072 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The molecule of the title compound, [Cu 2 (N 3 ) 2 (C 9 H 10 BN 6 ) 2 ], is located at a crystallographic inversion centre. The two Cu atoms have distorted square-pyramidal coordination and are bridged by two end-on azide groups. Weak CÐHÁ Á ÁN contacts result in a two-dimensional network with base

(4,7-Di­methyl-1,10-phenanthroline)­bis­
✍ Guo, Tengwen ;Lai, Chian Sing ;Tan, Xi Jie ;Teo, Chin Seng ;Tiekink, Edward R. T 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

(4,7-Di­methyl-1,10-phenanthroline)­bis(
✍ Soh, Shu Fang ;Lai, Chian Sing ;Tiekink, Edward R. T. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 197 KB

An N 2 S 2 -donor set de®nes the approximately tetrahedral coordination environment about the zinc centre in the monomeric title compound, [Zn(S 2 CO i Pr) 2 (4,7-Me 2 phen)] or [Zn(C 4 H 7 OS 2 ) 2 (C 14 H 12 N 2 )], which has crystallographically imposed twofold rotation symmetry.