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Di-μ-azido-bis{[hydro­tris­(pyrazol-1-yl)­borato]copper(II)}

✍ Scribed by Wang, Shi ;Li, Yi-Zhi ;Zuo, Jing-Lin ;You, Xiao-Zeng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
442 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The molecule of the title compound, [Cu 2 (N 3 ) 2 (C 9 H 10 BN 6 ) 2 ], is located at a crystallographic inversion centre. The two Cu atoms have distorted square-pyramidal coordination and are bridged by two end-on azide groups. Weak CÐHÁ Á ÁN contacts result in a two-dimensional network with base vectors [101] and [010], parallel to the (101) plane.

📜 SIMILAR VOLUMES

Carbonyl­[hydro­tris(3,5-di­methyl­pyraz
Carbonyl­[hydro­tris(3,5-di­methyl­pyrazol-1-yl)­borato]copper(I) aceto­nitrile solvate
✍ Blake, Alexander J. ;Carling, David A. ;George, Michael W. ;Hubberstey, Peter ;L 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 232 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.042 wR factor = 0.125 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.