Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.081 Data-to-parameter ratio = 23.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(μ-N-methyl-N-phenyldithiocarbamato)[bis(N-methyl-N-phenyldithiocarbamato)zinc(II)]
✍ Scribed by Baba, Ibrahim ;Lee, Lay Hoon ;Farina, Yang ;Othman, A. Hamid ;Ibrahim, Abdul Razak ;Usman, Awang ;Fun, Hoong-Kun ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 246 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
resulting white precipitate was ®ltered, washed with cold ethanol and dried in vacuo. Crystals suitable for X-ray analysis were obtained by recrystallization from a 1:1 mixture of ethanol and chloroform.
The trinuclear title compound, (" 2 -dppf){Cd(S 2 CNEt 2 ) 2 } 2 or [Cd 2 Fe(C 3 H 10 NS 2 ) 4 (C 21 H 14 P) 2 ], is disposed about a crystallographic centre of inversion and features ®ve-coordinate Cd atoms that exist in distorted square-pyramidal geometries de®ned by a PS 4 donor set.
Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.005 A Ê R factor = 0.028 wR factor = 0.063 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Sn(C 6 H 5 ) 3 {S 2 CN(Et)C 6 H 11 }], has a similar geometry to its methyl analogue, between tetrahedral and distorted trigonal bipyramidal but closer to the latter. The long intramolecular SnÁ Á ÁS interaction of 2.9426 (10) A Ê is slightly shorter than in its methyl analogue,
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.033 wR factor = 0.078 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.