Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.100 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
[μ-1,1′-Bis(diphenylphosphino)ferrocene-P,P′]bis[bis(N,N-diethyldithiocarbamato-S,S′)cadmium(II)]
✍ Scribed by Dee, Cathleen M. ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 287 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The trinuclear title compound, (" 2 -dppf){Cd(S 2 CNEt 2 ) 2 } 2 or [Cd 2 Fe(C 3 H 10 NS 2 ) 4 (C 21 H 14 P) 2 ], is disposed about a crystallographic centre of inversion and features ®ve-coordinate Cd atoms that exist in distorted square-pyramidal geometries de®ned by a PS 4 donor set.
📜 SIMILAR VOLUMES
The molecular structure of the title compound, [Zn 2 (C 4 H 7 OS 2 ) 4 (C 26 H 24 P 2 )], features two Zn(S 2 COiPr) 2 units bridged by a diphosphine ligand. The thiolate ligands are chelating but form asymmetric ZnÐS bonds, introducing considerable distortion in the coordination geometry about Zn t
Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
0 -Bis(diphenylphosphino)ferrocene-j 2 P,P 0 0 0 ]bis(2,3,4,5,6-pentafluorobenzenethiolato)platinum(II) Alejandra Garce ´s-Rodrı ´guez,