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Poly[[[aqua­(1,10-phenanthroline)cobalt(II)]-μ3-4-bromo­isophthalato] monohydrate]

✍ Scribed by Hu, Xin-Gen ;Xiao, Hong-Ping

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
291 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, {[Co(C~8~H~3~BrO~4~)(C~12~H~8~N~2~)(H~2~O)]·H~2~O}~n~, each Co^II^ ion is six-coordinated by three O atoms from three carboxylate groups of three 4-bromoisophthalate dianions, one water molecule, and two N atoms from a 1,10-phenanthroline ligand. The coordination geometry around the Co^II^ cation is octahedral. Whereas the 1,10-phenanthroline ligand chelates to just one Co^II^ cation, the 4-bromoisophthalate dianions are bonded to three Co^II^ cations. The crystal structure is stabilized by several hydrogen bonds.

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