In the title polymeric structure, {[Mn(C 8 H 3 NO 6 )(C 12 H 8 N 2 )]Á-H 2 O} n , the Mn atom adopts an octahedral geometry. The 2nitrobenzene-1,4-dicarboxylate ligand is in a chelating-bridging mode and its two carboxylate groups are approximately perpendicular to each other. The crystal structure
Poly[[(1,10-phenanthroline)(μ3-pyridine-2,3-dicarboxylato)manganese(II)] monohydrate]
✍ Scribed by Niu, Xue-Li ;Dou, Jian-Min ;Hu, Chang-Wen ;Li, Da-Cheng ;Wang, Da-Qi
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 306 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 292 K Mean (C-C) = 0.003 A R factor = 0.035 wR factor = 0.101 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title La^III^ complex, [La~2~(C~7~H~3~NO~4~)~3~(H~2~O)~5~]·H~2~O, forms a layer-type polymeric structure with La^III^ ions bridged by pyridine-3,4-dicarboxylate ligands. The asymmetric unit contains two La^III^ ions, the first exhibiting a distorted tricapped trigonal prismatic geometry (nine-co