✦ LIBER ✦

catena-Poly[[[aquaformato(1,10-phenanthroline)cobalt(II)]-μ-formato] monohydrate]

✍ Scribed by Zhou, Bin ;Zheng, Peng-Wu ;Liu, Ke-Yue

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 783 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807047162

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✦ Synopsis

In the polymeric title compound, {[Co(CHO~2~)~2~(C~12~H~8~N~2~)(H~2~O)]·H~2~O}~n~, the cobalt ion is coordinated by two N atoms from one chelating 1,10-phenanthroline ligand, three formate O atoms and one water O atom, giving a cis-CoN~2~O~4~ octahedral geometry. Pairs of formate anions bridge the metal atoms into a chain. A network of O—H...O hydrogen bonds helps to establish the packing.

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