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Aqua(3-carboxylatophenoxyacetato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II) tetrahydrate

✍ Scribed by Gao, Shan ;Ng, Seik Weng

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 194 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805038559

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✦ Synopsis

The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. Extensive hydrogen bonding leads to a three-dimensional network.

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✦ Synopsis

Aqua(3-carboxylatophenoxyacetato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II) tetrahydrate