Aquabis(1,10-phenanthroline-κ2N,N′)(2-sulfobenzoato-κO)manganese(II) trihydrate
✍ Scribed by Xiao, Hong-Ping
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 485 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Ce(C 6 H 4 NO 2 ) 3 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á-3H 2 O, the Ce III atom shows a capped trigonal prismatic N 4 O 5 coordination. The CeÐO and CeÐN bond distances are 2.390 (2)±2.517 (2) and 2.730 (3)±2.752 (3) A Ê , respectively.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.032 wR factor = 0.065 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Nd(C 6 H 4 NO 2 ) 3 (C 12 H 8 N 2 ) 2 molecule and three uncoordinated water molecules. The Nd III atom is nine-coordinate through coordination by the O atoms of three nicotinate groups, four N atoms of two phenanthroline molecules and two water molecules in a tricapped trigona