Aqua(3,5-dinitrosalicylato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 3,5-dinitrosalicylate
✍ Scribed by Song, Wen-Dong ;Yan, Jian-Bin ;Guo, Xian-Xia ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 221 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. E
The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa