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Tris(1,10-phenanthroline)nickel(II) squarate octa­hydrate

✍ Scribed by Uçar, İbrahim ;Yeşilel, Okan Zafer ;Bulut, Ahmet ;Ölmez, Halis ;Büyükgüngör, Orhan


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
301 KB
Volume
61
Category
Article
ISSN
1600-5368

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Tris(1,10-phenanthroline)­nickel(II) hex
✍ Wang, Wenju ;Xu, Lin ;Gao, Guanggang ;Wei, Yongge 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 443 KB

The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,1

Tris(1,10-phenanthroline)cobalt(II) trii
✍ Tershansy, Meredith A. ;Goforth, Andrea M. ;Smith, Mark D. ;Peterson Jr, LeRoy ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol

cis-Diaqua­bis(1,10-phenanthroline)nicke
✍ Chen, Jian-Mei ;Fan, Sai-Rong ;Zhu, Long-Guan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 262 KB

In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in