Tris(1,10-phenanthroline)nickel(II) squarate octahydrate
✍ Scribed by Uçar, İbrahim ;Yeşilel, Okan Zafer ;Bulut, Ahmet ;Ölmez, Halis ;Büyükgüngör, Orhan
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 301 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,1
The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol
In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in