Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê Disorder in solvent or counterion R factor = 0.052 wR factor = 0.135 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tris(phenanthroline-κ2N,N′)nickel(II) bis(malate) tetrahydrate
✍ Scribed by Yan, Guo-Bing
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 184 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. E
In the title compound, [Cu(C~12~H~6~N~2~O~2~)~3~](ClO~4~)~2~·4.5H~2~O, the Cu^II^ atom is in a distorted octahedral environment with unequal Cu—N distances, due to the Jahn–Teller elongation of the two Cu—N bonds in __trans__ positions. The crystal studied was an inversion twin..