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Tris(1,10-phenanthroline-5,6-dione-κ2N,N′)copper(II) bis(perchlorate) 4.5-hydrate

✍ Scribed by Khalaji, Aliakbar Dehno ;Slawin, Alexandra M. Z. ;Woollins, J. Derek

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
576 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, Cu(C~12~H~6~N~2~O~2~)~3~~2~·4.5H~2~O, the Cu^II^ atom is in a distorted octahedral environment with unequal Cu—N distances, due to the Jahn–Teller elongation of the two Cu—N bonds in trans positions. The crystal studied was an inversion twin..

📜 SIMILAR VOLUMES

Tris(1,10-phenanthroline-κ2N,N′)­zinc(II
Tris(1,10-phenanthroline-κ2N,N′)­zinc(II) bis­(perchlorate) ethanol solvate monohydrate
✍ Wei, Yibin ;Yuan, Caixia ;Yang, Pin 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 387 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Dichlorido(dimethyl sulfoxide-κO)(1,10-p
Dichlorido(dimethyl sulfoxide-κO)(1,10-phenanthroline-5,6-dione-κ2N,N′)copper(II) dimethyl sulfoxide monohydrate
✍ Xu, Guang-Jun ;Xie, Ming-Jin ;Feng, Li ;Yan, Shi-Ping ;Liao, Dai-Zheng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 559 KB

The title compound, [CuCl 2 (C 12 was obtained by the reaction of 1,10-phenanthroline-5,6-dione (phendione) and CuCl 2 Á2H 2 O. The copper(II) ion is pentacoordinated in a distorted squarepyramidal environment. The water molecule connects the complex and a dimethyl sulfoxide solvent molecule by O-H