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Tris(1,10-phenanthroline-κ2N,N′)­zinc(II) bis­(perchlorate) ethanol solvate monohydrate

✍ Scribed by Wei, Yibin ;Yuan, Caixia ;Yang, Pin


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
387 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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Tris(1,10-phenanthroline-5,6-dione-κ2N,N
✍ Khalaji, Aliakbar Dehno ;Slawin, Alexandra M. Z. ;Woollins, J. Derek 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 576 KB

In the title compound, [Cu(C~12~H~6~N~2~O~2~)~3~](ClO~4~)~2~·4.5H~2~O, the Cu^II^ atom is in a distorted octahedral environment with unequal Cu—N distances, due to the Jahn–Teller elongation of the two Cu—N bonds in __trans__ positions. The crystal studied was an inversion twin..