Diaquabis(1,10-phenanthroline-κ2N,N′)zinc(II) pamoate monohydrate
✍ Scribed by Ma, Ai-Qing ;Jia, Zhen-Bin ;Wang, Guo-Ping
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 274 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction of 3,5-diaminobenzoic acid, 1,10-phenanthroline, NaN 3 and Zn II in basic aqueous solution gave rise to the title compound, The Zn II atom is six-coordinate with a distorted octahedral geometry. The two aqua ligands are in cis positions and the 3,5-diaminobenzoate ligand binds to the c
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title complex, [Co(C 7 H 5 O 3 ) 2 (C 12 H 8 N 2 )(H 2 O) 2 ]ÁH 2 O, displays a distorted octahedral coordination geometry about the Co II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline (phen) molecule and two water molecules. The face-to-face distance of 3.420 (5) A ˚betw
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.