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Diaqua­azido­(3,5-diamino­benzoato-κN)(1,10-phenanthroline-κ2N,N′)zinc(II) monohydrate

✍ Scribed by Li, Ming-Xing ;Zhao, Hong-Jian ;Shao, Min ;Miao, Zhi-Xin ;Zhou, Shou-Rong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
92 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The reaction of 3,5-diaminobenzoic acid, 1,10-phenanthroline, NaN 3 and Zn II in basic aqueous solution gave rise to the title compound,

The Zn II atom is six-coordinate with a distorted octahedral geometry. The two aqua ligands are in cis positions and the 3,5-diaminobenzoate ligand binds to the central Zn atom through one of its amino groups.

📜 SIMILAR VOLUMES

Diaqua­bis(3-hydroxy­benzoato-κO)bis­(1,
Diaqua­bis(3-hydroxy­benzoato-κO)bis­(1,10-phenanthroline-κ2N,N′)barium(II)
✍ Liu, Ji-Wei ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 255 KB

The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.

Aqua­(dipicolinato-κ3O,N,O′)(1,10-phenan
Aqua­(dipicolinato-κ3O,N,O′)(1,10-phenanthroline-κ2N,N′)zinc(II) monohydrate
✍ Harrison, William T. A. ;Ramadevi, Palani ;Kumaresan, Sudalaiandi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 472 KB

The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa

Aqua­bis(4-formyl­benzoato-κO)(1,10-phen
Aqua­bis(4-formyl­benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.003 A R factor = 0.033 wR factor = 0.088 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.