In the title complex, {[Cu(C 8 H 4 O 4 )(C 12 H 8 N 2 )(H 2 O)]Á-C 3 H 7 NOÁH 2 O} n , the Cu atom is surrounded by two O atoms from two isophthalate dianions, an aqua O atom and two N atoms from a phenanthroline heterocycle in a distorted square-pyramidal geometry. The isophthalate dianion function
✦ LIBER ✦
Aquabenzoatobis(1,10-phenanthroline-κ2N,N′)manganese(II) perchlorate dimethylformamide solvate
✍ Scribed by Zhang, Xiaofeng ;Fan, Cheng ;Wang, Wenguo ;Chen, Changneng ;Liu, Qiutian
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 240 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.