Rate constants for base hydrolysis of the trzs-( 1,lO-phenanthroline)iron(II) cation and for solvolysis of the cis-dichlorobis(l,2-ethanediamine)cobalt(III~ cation have been measured in binary aqueous mixtures containing l,a-ethanediol, 1,2or 1,4-butanediol, 1,2-or 1,6-hexanediol, 1-propanol, or t-b
cis-Dichlorobis(1,10-phenanthroline)cobalt(II)
✍ Scribed by Zhong, H. ;Zeng, X.-R. ;Luo, Q.-Y.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 830 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
As a result of problems with the data sets and incorrect atom assignments, 41 papers by H. Zhong et al. are retracted. Full details of all the articles are given in Table 1.
📜 SIMILAR VOLUMES
In the title compound, cis-[FeCl 2 (C 12 H 8 N 2 ) 2 ], the Fe atom has a distorted octahedral coordination composed of four N atoms from two phenanthroline groups and two Cl atoms. The crystal packing is stabilized by weakstacking of neighboring phenanthroline groups.
Single-crystal X-ray study T = 200 K Mean '(C±C) = 0.009 A Ê R factor = 0.040 wR factor = 0.091 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
metal-organic papers m106 Xie, He, Zhou andZhu [Co(C 8 H 4 NO) 2 (C 12 H 8 N 2 )(H 2 O) 2 ] Acta Cryst. (2004). E60, m105±m107