Rate constants at room temperature for the reactions of oxygen with Sn~ (n= 1-9) and Pb~-(n= 1-7) cluster anions are reported from flow-tube reactor kinetics measurements. A large variation in reactivity for different cluster sizes is observed, with reaction efficiencies ranging from 2% to 30% of th
Thermal metal cluster anion reactions: Behavior of aluminum clusters with oxygen
β Scribed by Leuchtner, R. E.; Harms, A. C.; Castleman, A. W.
- Book ID
- 121313962
- Publisher
- American Institute of Physics
- Year
- 1989
- Tongue
- English
- Weight
- 413 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.456988
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π SIMILAR VOLUMES
Reactions of cooled, size-selected aluminum cluster ions (Al: , n = l-8) with oxygen have been studied at collision energies from 0.15 to 10.0 eV (center-of-mass) under single-collision conditions. With the exception of the atomic ion, all size clusters undergo exoergic reactions which result in ext
The reaction of aluminum clusters, Al, (n = 7-24), formed by laser vaporization, with oxygen and ammonia was studied by using a fast flow reactor. It was found that the oxygen reacts strongly with aluminum clusters to form chemisorbed products while ammonia is adsorbed weakly with Al, in a physisorb